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Setting up some #NMR measurements from home thanks to VPN and remote access to my office computer. Thanks to the IT Department and my colleagues at #MPIKofo for making this possible ❤️ Max Planck Society #Homeoffice #NMRchat

Finally Online 🙃 Together with my colleagues from the Fürstner group we today report some new advances for alkyne metathesis. The work also includes some 95Mo #NMR studies and great insights from DFT-based chemical shift tensor analysis by Copéret Group / @coperetgroup.bsky.social pubs.acs.org/doi/10.1021/ja…

Another nice collaboration with my colleagues from AK List

Another chapter in the recent work on Alkyne metathesis together with the #FürstnerLab and Copéret Group / @coperetgroup.bsky.social. This time we managed to use the cinderella nucleus 183W to guide our studies.

It’s great seeing it finally online 🙂 It was a pleasure being part of the team 👌

The next collaboration with my colleagues from the Fürstner group: This time we report how [Cp*RuCl]4 can catalyze trans-hydro- and trans-chloroalkynylations of internal alkynes and give some mechanistic insights from X-Ray structures and NMR studies. pubs.acs.org/doi/10.1021/ja…

This trans-hydrogenation reaction and PHIP studies on it was a part of my PhD work. It’s great to see such advances on that 👍

Yet another collaboration with the colleagues from the Fürstner and Neese groups at #MPIKofo. This time we report more detailed mechanistic insights into alkyne metathesis with the "Canopy Catalysts". pubs.acs.org/doi/10.1021/ja…

Happy to share a new triple resonance approach for the detection of #103Rh #NMR Shifts together with my colleagues from #MPIKofo pubs.acs.org/doi/10.1021/ja…

Reporting in J. Am. Chem. Soc.: low-valent Bi redox catalysis via elementary organometallic steps: catalytic hydrodefluorination. Excellent work by Yue (Yue Pang) Markus (Markus L.), Nils and Felix! pubs.acs.org/doi/10.1021/ja…

Congratulations to Ben List and all the new and former colleagues from AK List 🥳🥳🥳

Hydrogenative Cycloisomerization and Sigmatropic Rearrangement Reactions of Cationic Ruthenium Carbenes Formed by Catalytic Alkyne gem-Hydrogenation (Fuerstner) Max Planck Society #OpenAccess thanks to #ProjektDEAL onlinelibrary.wiley.com/doi/10.1002/an…

#nmrchat

How does the reductive elimination of aryl-F from Bi(V) work?🤔 Check out my last dance with Cornellab, a HUGE study that includes kinetics, DFT, 23 (!) X-ray structures and improved stoichiometric and catalytic methodologies to furnish fluoroarenes! pubs.acs.org/doi/10.1021/ja…

What an interesting & initially puzzling project to be part of. Thanks to the whole team, but especially Yue Pang.

This is a very impressive NMR setup - I was a postdoc at MRRC Cambridge back when the whole setup was installed and it’s nice to see where it end up - I recommend reading the paper 😀

JUST PUBLISHED: Harry Harbor-Collins's first paper; a step towards making rhodium NMR fast and accessible. Another fun collaboration with Markus L.! pubs.aip.org/aip/jcp/articl…

doi.org/10.1063/5.0182… Freshly published, another 103Rh NMR paper - this time exotic! Rh-Rh J-couplings, 18O secondary isotope shifts and the first ever reported 103Rh Singlet State (This is the Levitt Research Group after all!) Mohamed Sabba Markus L.

I'm excited to finally share my favorite project from my PhD journey at Cornellab (w/ Hye Won (Hanna) Moon , Markus L. , Nils.Not , & Vanessa Béland : the monomeric triarylbismuthine oxide💎- the missing piece of the pnictine oxide series 🧩! doi.org/10.1002/anie.2…

Red-Light-Active N,C,N-Pincer Bismuthinidene: Excited State Dynamics and Mechanism of Oxidative Addition into Aryl Iodides | Journal of the American Chemical Society @Totalsynth Cornellab Mauro Mato Markus L. Marcos Gil Sepulcre Alejandro Cadranel pubs.acs.org/doi/10.1021/ja…