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Unveiling a new paradigm of chemical reactivity: A well-defined chemical starting material decays spontaneously at cryogenic temperatures into two different products that arise from heavy-atom carbon vs. nitrogen tunneling. #JustAccepted acspubs.co/ZrjH30pqRik

Heavy‐Atom Tunneling Through Crossing Potential Energy Surfaces: Cyclization of a Triplet 2‐Formylarylnitrene to a Singlet 2,1‐Benzisoxazole onlinelibrary.wiley.com/doi/10.1002/an…

Heavy-Atom Tunneling Through Crossing Potential Energy Surfaces: Cyclization of a Triplet 2-Formylarylnitrene to a Singlet 2,1-Benzisoxazole (Fausto) onlinelibrary.wiley.com/doi/10.1002/an…

Bond-Breaking/Bond-Forming Reactions by Vibrational Excitation: Infrared-Induced Bidirectional Tautomerization of Matrix-Isolated Thiotropolone pubs.acs.org/doi/10.1021/ac…

Just Published: Switching on H-Tunneling through Conformational Control bit.ly/3yH7nlH

Inducing Molecular Reactions by Selective Vibrational Excitation of a Remote Antenna with Near-Infrared Light - now published in Chemical Communications pubs.rsc.org/en/content/art…

Photochromism of a Spiropyran in Low-Temperature Matrices: Unprecedented Bidirectional Switching between a Merocyanine and an Allene Intermediate pubs.acs.org/doi/10.1021/ac…

Just Published: Simultaneous Tunneling Control in Conformer-Specific Reactions dx.doi.org/10.1021/jacs.2…

Two conformers undergoing different quantum tunnelling processes ‘is completely breaking the classic transition state rules’ – Kat reports on the discovery chemistryworld.com/news/unprecede…

Conformers Undergo Different Reactions Controlled by Quantum Tunneling: Unprecedented reaction gives distinct rearrangement products that cannot be explained by classical reactivity models bit.ly/3XwutYj

Hydrogen Tunneling Exhibiting Unexpectedly Small Primary Kinetic Isotope Effects (Claudio M. Nunes Cláudio M. Nunes and co-workers PRS-Group) onlinelibrary.wiley.com/doi/10.1002/ch…

Competitive Heavy-Atom Tunneling Reactions Controlled Through Electronic Effects by Claudio M. Nunes, Peter R. Schreiner, and co-workers (Cláudio M. Nunes, Universidade de Coimbra, PRS-Group, Universität Gießen) #OpenAccess Chemistry Europe onlinelibrary.wiley.com/doi/10.1002/ce…

🧪 Cláudio M. Nunes & Peter R. Schriner ( PRS-Group ) discuss how electron-donating substituents can control quantum mechanical tunneling (QMT) reactivity—and why QMT deserves a place in general chemistry curricula chemistryviews.org/tuning-quantum…