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Electrophilic C(sp2)-H Cyanation with Inorganic Cyanate (OCN-) by PIII/PV=O-Catalyzed Phase Transfer Activation (Alexander T. Radosevich and co-workers) MIT Chemistry #openaccess Shicheng Hu onlinelibrary.wiley.com/doi/10.1002/an…

Happy to share my undergraduate research in Radosevich Lab MIT Chemistry published!

Activation and Catalytic Degradation of SF6 and PhSF5 at a Bismuth Center | Journal of the American Chemical Society Cornellab #SF6 #PhSF5 #Bismuth pubs.acs.org/doi/10.1021/ja…

Really proud of this one! 😊 I got to lean into my training, expand my skill set and broaden my perspective! Thanks to everyone in Cornellab for useful discussions and moral support (proud to be on this team), collaborators Nils.Not & Markus L. and @NSERC for funding!

Toast to the bimetallic team in our group for our first TM-based chemistry published in J. Am. Chem. Soc. We introduced a new platform for the mimicry of Cu-ZSM-5, highlighting the role of aluminum in hydrogen atom abstraction reactivity! Way to go! doi.org/10.1021/jacs.4…

Now out! Activation and C‒C Coupling of Aryl Iodides via Bismuth Photocatalysis. onlinelibrary.wiley.com/doi/10.1002/an… Check our last report from Cornellab, achieving the catalytic formation of C(sp2)-C(sp2) bonds with bismuth, using not only 1 but 2 photochemical steps!

I'm excited to finally share my favorite project from my PhD journey at Cornellab (w/ Hye Won (Hanna) Moon , Markus L. , Nils.Not , & Vanessa Béland : the monomeric triarylbismuthine oxide💎- the missing piece of the pnictine oxide series 🧩! doi.org/10.1002/anie.2…

The third article of Cornellab Bi ACIE trilogy this week! Check out the structure of monomeric iminobismuthanes (work done w/ Nils.Not, Markus L., and Jennifer Kuziola): onlinelibrary.wiley.com/doi/10.1002/an…

Interested in some more nice monomeric Bi structures 🔎? Then, have a look on newest article about iminobismuthanes ⬇️⬇️⬇️!

What happens when you mix carboxylic acids and pyridines? Acid-base reaction? You are only partially right. Check our latest article, isocyanates can greatly enhance the photochemical expansion of pyridines to 1,2-diazepines! @ILV_UMR8180 @XMoreau_ILV onlinelibrary.wiley.com/doi/10.1002/ad…

sciencedirect.com/science/articl… Our paper on the synthesis of securingine B and its application into the development of a new photoswitch is out Chem. Congrats Sangbin and Gyumin Kang, and our collaborators, especially Prof. Dongki Yoon. KAIST Chemistry KAISTPR #totalsynthesis

Characterization of Iminobismuthanes and Catalytic Reduction of Organic Azides via Bi(I)/Bi(III) Redox Cycling (Josep Cornella and co-workers) @hyewon_moon @Nils_Not Markus L. Jennifer Kuziola Cornellab #openaccess onlinelibrary.wiley.com/doi/10.1002/an…

Direct Determination of a Giant Zero-Field Splitting of 5422 cm–1 in a Triplet Organobismuthinidene by Infrared Electron Paramagnetic Resonance | JACS Cornellab #ZeroFieldSplitting #Organobismuthinidene #IR #Paramagentic #Resonance pubs.acs.org/doi/10.1021/ja…

Our manuscript “A trimetallic bismuth(I)-based allyl cation” is now online! Check it out: nature.com/articles/s4155… Nature Chemistry Diving into the dark side of Inorg Chem was a pleasure with Cornellab Nils.Not Markus L. F. Neese, M. Van Gastel, and L. Wagner!

Excited to share our work (Eunsung Lee) in collaboration with Prof. Tae-Lim Choi's group! Air-stable ruthenium catalysts with tethered CAAC ligands for REMP. A heartfelt thank you to the reviewers and editor for their invaluable advice! doi.org/10.1021/jacs.4…

Join us for the MGC (IOS/Sage) webinar next week! I'll be presenting Pn redox chemistry that I worked on during my PhD and postdoc.

We are looking for a new postdoc to join Lipshultz Group to work on synthetic methods enabled by catalytic photochemistry of catalyst-substrate complexes! Please apply here by May 8: stonybrooku.taleo.net/careersection/… #chempostdoc

🚨Out! Red-shifted activation and coupling of RAEs using NADH as bio-reductant. First steps towards integrating alkyl radical chemistry in biological settings. Huge effort by David and Uxía! CiQUS Mascareñas group Thanks OBC for the invitation! pubs.rsc.org/en/content/art…

🎉 Proud moment! Our Main Group team just published their 2nd paper in JACS Au! They uncovered how O₂ activation mechanisms differ across P, Sb, and Bi - pushing the boundaries of main group chemistry 🧪 Read more: pubs.acs.org/doi/10.1021/ja…

Zwitterionic Heavier Pnictinidenes in Redox Catalysis (Oriol Planas and co-workers) #AngewandteVIP #openaccess 🔓 onlinelibrary.wiley.com/doi/10.1002/an…